Mwafak Shakoor

Power-to-Ammonia-to-Power (P2A2P) systems in hot-arid MENA climates reject waste heat through Recuperated Organic Rankine Cycles (RORCs) whose condensation temperature tracks ambient conditions across annual swings exceeding 35 K. Standard exergoenvironmental assessments evaluate priorities at a single dead-state temperature, an assumption this study terms the Static $T_0$ Fallacy. A four-way advanced exergy decomposition is combined with an off-design model (Stodola’s ellipse, constant-$UA$ scaling) to sweep the dead-state temperature from ${5 }^{\circ }$C to ${40 }^{\circ }$C. At $T_0={20 }^{\circ }$C, 95.8% of total exergy destruction is endogenous, confirming weak inter-component coupling. The condenser carries the largest avoidable environmental impact rate (4.02 mPts/h, 74% of the system total). At $T_0={37.4 }^{\circ }$C, the recuperator undergoes a priority inversion from destruction-dominated ($f_b=14.7\%$) to fully capital-dominated ($f_b=100\%$). Ammonia’s wet-fluid thermodynamic coupling eliminates the recuperator’s duty as the condensation temperature approaches the cold-side outlet constraint. The recuperator’s avoidable environmental impact rate drops by 100% relative to the standard assessment, while the condenser’s rises by 49%. This inversion mechanism is fluid-specific: the ammonia recuperator’s endogenous fraction reaches 99.5% at $T_0={20 }^{\circ }$C. The toluene recuperator, swept at its own independently optimised operating point, has an endogenous fraction between 59.08% and 82.31% over the same range. For P2A2P installations where the annual ambient swing exceeds 15 K, exergoenvironmental analysis should be performed at both design-season and summer-peak dead-state temperatures, with the summer-peak result governing capital allocation.

Non-insulated heat exchangers in gas-to-gas service lose substantial energy to the surroundings. This study evaluates Al₂O₃ and ZnO ceramic coatings (200 $\mathsf{\mu }$m) as passive thermal retention layers on the inner surface of the outer tube in a copper double-pipe heat exchanger, using 3D CFD simulations verified for internal consistency against Log Mean Heat Transfer Rate analytical solutions. Six cases were modelled: three coating conditions across parallel-flow and counter-flow configurations under laminar conditions ($R{e}_i\approx 525$, $R{e}_o\approx 192$) with air as the working fluid. The coating elevates the outer tube inner wall temperature $T_3$, increasing the convective driving force to the cold fluid while suppressing ambient dissipation. In parallel flow, Al₂O₃ increases the net inter-fluid heat transfer rate by 35.7% and reduces ambient losses by 81.4%; ZnO achieves 30.9% and 70.4%, respectively. In counter-flow, Al₂O₃ yields a 26.6% enhancement and 73.2% loss reduction. The coated parallel-flow configuration outperforms the uncoated counter-flow baseline. Thermal circuit analysis shows that Al₂O₃ superiority arises from its higher conductivity (40 vs. 19 W m⁻¹ K⁻¹), which sustains a higher equilibrium $T_3$ and a heat partition ratio of 11.84 versus 7.17 for ZnO. These results show that a single ceramic coating layer can recover a large fraction of the thermal energy lost through non-insulated walls, offering a low-cost, retrofit-compatible pathway to improve the energy efficiency of gas-to-gas heat exchangers in HVAC, building energy recovery, and industrial process heat applications.