MRManuel A. Rodriguez

Manuel A. Rodriguez

*This is an algorithmically generated author record based on publicly available information.

Current Organizations / Institutes

The organizations/institutes from the scholar's latest article


Manuel A. Rodriguez has a total of 22 co-authors. Here are the top co-authors by number of shared publications:


Latest Publications

  • Conformal oxides decouple chemical stability and energetics at NiO x /perovskite interfaces

    by Chenchao Xie, Shuai You, Melissa A. Davis, Ross A. Kerner, Kelly Schutt, Ryan A. DeCrescent, Tianran Liu, Manuel A. Rodriguez, Rosemary C. Bramante, Christian Velez, et al.

    Nickel oxide (NiO x ) is a common hole transport layer (HTL) in perovskite photovoltaics, but the chemical reactivity of NiOx surfaces accelerates degradation when contacting perovskites. We developed an ultrathin, conformal tin oxide (SnO x ) interlayer to suppress interfacial reactivity between NiO x and perovskite. SnO x is typically an electron transport layer, but we show that the energy alignment can be modified for hole extraction using molecules with dipoles. This synergy yielded high efficiency in perovskite photovoltaic devices and showed an ~10x improvement in T 90 lifetime in open-circuit conditions under AM1.5G at 65°C. This structure also improves resilience to thermomechanical durability, as minimodules retained 95.7% of their initial performance after 1000 thermal cycles (−65° to 85°C), highlighting the importance of interfaces for robust perovskite photovoltaic modules.